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Equilibrium acidities of HA2+ dications in dimethyl sulfoxide solution
- Source :
- Journal of Organic Chemistry. May 20, 1994, Vol. 59 Issue 10, p2809, 4 p.
- Publication Year :
- 1994
-
Abstract
- A combination of the equilibrium acidities of weak acids with the oxidation potential of the acid and those of the corresponding A(super -) anions, A(super -) radicals, and HA(super +) radical cations enables the estimation of the acidities of HA(super 2+)-type dications. The instability of the radical cation prevents the measurements of the oxidation potential by cyclic voltammetry. The oxidation potentials of three acids are measured and examined.
- Subjects :
- Cations -- Research
Chemical equilibrium -- Analysis
Biological sciences
Chemistry
Subjects
Details
- ISSN :
- 00223263
- Volume :
- 59
- Issue :
- 10
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.16082924