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Infrared spectra of chlorinated ethylene cations: [C.sub.2][Cl.sub.4.sup.+], [C.sub.2]H[Cl.sub.3.sup.+], 1,1-[C.sub.2][H.sub.2][Cl.sub.2.sup.+], and trans-[C.sub.2][H.sub.2][Cl.sub.2.sup.+] in solid argon

Authors :
Han Zhou
Yu Gong
Mingfei Zhou
Source :
Journal of Physical Chemistry A. Feb 1, 2007, Vol. 111 Issue 4, 603-609
Publication Year :
2007

Abstract

Infrared spectra of chlorinated ethylene cations such as [C.sub.2][Cl.sub.4.sup.+], [C.sub.2]H[Cl.sub.3.sup.+], 1,1-[C.sub.2][H.sub.2][Cl.sub.2.sup.+], and trans-[C.sub.2][H.sub.2][Cl.sub.2.sup.+] isolated in solid argon, is presented. The results show that the cations can be regarded as 'isolated' with the vibrational frequencies which are slightly shifted compared to the available gas-phase values.

Details

Language :
English
ISSN :
10895639
Volume :
111
Issue :
4
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.159881126