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Cycloalkane and cycloalkene C-H bond dissociation energies
- Source :
- Journal of the American Chemical Society. Dec 27, 2006, Vol. 128 Issue 51, p17087, 6 p.
- Publication Year :
- 2006
-
Abstract
- A thermodynamic cycle is used to carry out several proton affinity, as well as electron-binding measurements, which are then used to effectively and accurately measure the cycloalkane and cycloalkene carbon-hydrogen (C-H) bond dissociation energies in the gas phase. The results show that the normally cited bond energies for such cyclic hydrocarbons are much smaller than their actual values, while a vast difference is observed between the actual and calculated values of their bond strengths.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 128
- Issue :
- 51
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.159059715