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Mechanism of the OH-initiated oxidation of glycoaldehyde over the temperature range 233-296 K

Authors :
Butkovskaya, Nadezhda I.
Pouvesle, Nicolas
Kukui, Alexandre
Le Bras, Georges
Source :
Journal of Physical Chemistry A. Dec 21, 2006, Vol. 110 Issue 50, p13492, 8 p.
Publication Year :
2006

Abstract

A study of the mechanism of the gas-phase OH initiated oxidation of glycoaldehyde in the 233-296 K temperature range using a turbulent flow reactor coupled with a chemical ionization mass spectrometer is presented. Formaldehyde, C[O.sub.2], formic acid and glyoxal were observed at RT with the yields of 80, 34, 18 and 14% respectively, in the presence of oxygen and decrease of temperature to 233K led to significant change in the yields of stable products.

Details

Language :
English
ISSN :
10895639
Volume :
110
Issue :
50
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.158121584