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2,3-anti selective aldol reaction of phenylacetonitrile
- Source :
- Journal of Organic Chemistry. July 29, 1994, Vol. 59 Issue 15, p4053, 3 p.
- Publication Year :
- 1994
-
Abstract
- NMR spectra and HPLC studies of the stereoselective and regioselective addition of a nitrile anion to aldehydes reveals that the reaction involves an intermediate that is a ketenimine-like N-lithiated-nitrile anion. Concentration studies optimize the reaction between benzaldehyde and lithiated phenylacetonitrile.
Details
- ISSN :
- 00223263
- Volume :
- 59
- Issue :
- 15
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.15724341