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Synthesis and biradicaloid character of doubly linked corrole dimers

Authors :
Hiroto, Satoru
Furukawa, Ko
Shinokubo, Hiroshi
Osuka, Atsuhiro
Source :
Journal of the American Chemical Society. Sept 27, 2006, Vol. 128 Issue 38, 12380-12381
Publication Year :
2006

Abstract

The synthesis and characterization of doubly linked corrole dimers are reported. The oxidize bis-zinc complex among the doubly linked corrole dimers is found to show unusual biradical character, reveals a planar cyclooctatetraene core and shows high stability in the air at ambient temperature.

Details

Language :
English
ISSN :
00027863
Volume :
128
Issue :
38
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.154178650