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Reactions of thiyl radicals with transition-metal complexes
- Source :
- Journal of the American Chemical Society. Nov 18, 1992, Vol. 114 Issue 24, p9510, 7 p.
- Publication Year :
- 1992
-
Abstract
- The laser flash photolysis study of thiyl radical reactions reveals that thiyl radicals oxidize reduced transition-metal complexes. Inner-sphere reagents react with ethylthiyl radicals to form metal-sulfur bonds. Outer-sphere reagents yield thiolate ions and oxidized metal complexes upon reaction with ethylthiyl radicals.
- Subjects :
- Transition metals -- Research
Thiols -- Research
Chemistry
Subjects
Details
- ISSN :
- 00027863
- Volume :
- 114
- Issue :
- 24
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.15369271