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Polyhedral skeletal isomerization in the octanuclear cluster (Re7IrC(CO)23)2-
- Source :
- Journal of the American Chemical Society. Jan 26, 1994, Vol. 116 Issue 2, p787, 2 p.
- Publication Year :
- 1994
-
Abstract
- An analysis of the octanuclear, mixed-metal cluster compound (Re7IrC(CO)23)(super 2-) confirms the presence of an intramolecular nondegenerate rearrangement. This is significant owing to its symmetry which brings into question contemporary conceptual ideas on transition metal cluster rearrangements. The energetics can be compared to that of Re/Ir heterometallic surfaces' metal atom mobilities.
- Subjects :
- Rearrangements (Chemistry) -- Research
Transition metals -- Research
Chemistry
Subjects
Details
- ISSN :
- 00027863
- Volume :
- 116
- Issue :
- 2
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.15276420