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Most stable metallic phase of the mixed-valence MMX-chain, Pt2(dtp)4l (dtp = C2H5C[S.sub.2.sup.-]), in purely d-electronic conductors based on the transition-metal complex
- Source :
- Journal of the American Chemical Society. June 28, 2006, Vol. 128 Issue 25, 8140-8141
- Publication Year :
- 2006
-
Abstract
- The electrical resisitivity and x-ray diffraction measurements for the MMX-chain complex, [Pt.sub.2][(dtp).sub.4)]I were performed under high pressure. The suppression of the metal-insulator transition to 70 K, the lowest known for any one-dimensional purely d-electronic conductors based on transition-metal complexes at 2.2 GPa is observed.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 128
- Issue :
- 25
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.149580368