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Probing the 3d spin momentum with X-ray emission spectroscopy: The case of molecular-spin transitions
- Source :
- Journal of Physical Chemistry B. June 22, 2006, Vol. 110 Issue 24, p11647, 7 p.
- Publication Year :
- 2006
-
Abstract
- X-ray emission spectra of [Fe.sup.III], [Fe.sup.II] and [Co.sup.II] spin-crossover compounds in their high-spin and low-spin forms are described. It is shown that all X-ray emission features are sensitive to the spin state and they reveal the details of the redistribution of electrons on the three-dimensional levels associated with the spin-state change revealing features at the X-ray absorption preedge.
Details
- Language :
- English
- ISSN :
- 15206106
- Volume :
- 110
- Issue :
- 24
- Database :
- Gale General OneFile
- Journal :
- Journal of Physical Chemistry B
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.148301282