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Hybrid organic-inorganic conductor with a magnetic chain anion: k-BETS2[Fe(super III)(C2O4)Cl2] [BETS = bis(ethylenedithio)tetraselenafulvalene]

Authors :
Bin Zhang
Zheming Wang
Yan Zhang
Takahashi, Kazuyuki
Okano,Yoshinori
Hengbo Cui
Kobayashi, Hayao
Inoue, Katsuya
Kurmoo, Mohamedally
Pratt, Francis L.
Daoben Zhu
Source :
Inorganic Chemistry. April 17, 2006, Vol. 45 Issue 8, p3275, 6 p.
Publication Year :
2006

Abstract

The synthesis, crystal structure, and electrical, optical, and magnetic properties of k-BETS2[Fe(super III)(C2O4)CI2] where BETS is bis(ethylenedithio)tetraselenafulvalene, are reported. It is an organic-inorganic hybrid that displays the coexistence of two-dimensional (2D) pi electrons, 1D antiferromagnetism, and possible canted antiferromagnetism involving pi and d spins.

Details

Language :
English
ISSN :
00201669
Volume :
45
Issue :
8
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.146105124