Color tuning of a nickel complex with a novel N(sub 2)S(sub 2) pyridine-containing macrocyclic ligand

Authors :: Tamayo, Abel
Brondino, Carlos D.
Casabo, Jaume
Kivekas, Raikko
Escriche, Lluis
Sillampaa, Reijo
Lodeiro, Carlos
Covelo, Berta
Source :: Inorganic Chemistry. Feb 6, 2006, Vol. 45 Issue 3, p1140, 10 p.
Publication Year :: 2006
Abstract: The novel pyridine-containing 14 membered macrocycle 3,11-dithia-7,17-diazabicyclo[11.3.1]heptadeca-1(17),13,-15-triene (L), which contains an N(sub 2)S(sub 2) donor set was synthesized and its protonation behavior was studied. The reactions between L and NiX(sub 2).6H(sub 2)O in ethanol or acetonitrile afforded the octahedral complexes and the square -planar complex [Ni(L)]-(X)(sub 2) were obtained by heating these octahedral complexes.

Subjects :: Nickel compounds -- Structure
Nickel compounds -- Chemical properties
Pyridine -- Structure
Pyridine -- Chemical properties
Alcohol -- Structure
Alcohol -- Chemical properties
Alcohol, Denatured -- Structure
Alcohol, Denatured -- Chemical properties
Acetonitrile -- Structure
Acetonitrile -- Chemical properties
Chemistry

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