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Synthesis, structure, and unusual reactivity of beta-halovinyl cobalt porphyrin complexes
- Source :
- Inorganic Chemistry. March 6, 2006, Vol. 45 Issue 5, p2288, 8 p.
- Publication Year :
- 2006
-
Abstract
- The synthesis, structures and reactivity of tetraphenylporphyrin (TPP) cobalt halovinyl complexes are described. The mechanism of halide substitution for the beta-halovinyl complexes is examined with kinetic experiments that showed a dissociative mechanism and supported the intermediacy of a cobalt acetylene complex.
- Subjects :
- Porphyrins -- Structure
Porphyrins -- Chemical properties
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 45
- Issue :
- 5
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.145602960