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Theoretical characterization of the 'very rapid' Mo(V) species generated in the oxidation of xanthine oxidase
- Source :
- Inorganic Chemistry. March 6, 2006, Vol. 45 Issue 5, p2199, 4 p.
- Publication Year :
- 2006
-
Abstract
- Density functional theory (DFT) calculations of the 'very rapid' Mo(V) intermediate of xanthine oxidase (XO) are presented. The results have suggested that the structure of the intermediate contains the substrate bonding to the metal in end-on coordination with a bond distance of 3.1-3.2 Angstrom.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 45
- Issue :
- 5
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.145600439