Natural bond orbital analyses of persulfoxide stabilization by remote functional groups: The conformationally induced electrostatic stabilization sulfide photooxygenation mechanism

The conformationally induced electrostatic stabilization (CIES) sulfide photooxygenation mechanism was computationally examined using an ab initio model and extended to the study of new donor atoms. The MP2/6-31G(d) geometries and a natural population analysis of natural lone-pair orbitals on the donor atoms support the mechanism and reveal that oxygen and nitrogen donor groups are more stabilizing than sulfur.