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Alkyne hydrosilylation catalyzed by a cationic ruthenium complex: Efficient and general trans addition
- Source :
- Journal of the American Chemical Society. Dec 21, 2005, Vol. 127 Issue 50, p17644, 12 p.
- Publication Year :
- 2005
-
Abstract
- The complex [Cp*Ru(MeCN)3]PF6 is shown to catalyze the hydrosilylation of a wide rage of alkynes. The same complex is active in internal alkyne hydrosilylation, where absolute selectivity for the trans addition process is maintained.
- Subjects :
- Ruthenium -- Chemical properties
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 127
- Issue :
- 50
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.144086801