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Magnetic polyoxometalates: Anistropic exchange interactions in the Co3(super II) moiety of [(NaOH2)CO3(H20)(P2W15O56)2](super 17-)

Authors :
Clemente-Juan, Juan Modesto
Coronado, Eugenio
Gaita-Arino, Alejandro
Gimenez-Saiz, Carlos; GUdel, Hans-Ulrich
Sieber, Andreas
Bircher, Roland; Mutka, Hannu
Source :
Inorganic Chemistry. May 16, 2005, Vol. 44 Issue 10, p3389, 7 p.
Publication Year :
2005

Abstract

The magnetic exchange interactions in a Co3(super II) moiety encapsulated in Na17 [(NaOH2)CO3(H20)(P2W15O56)2] (NaCo3) is studied by a combination of magnetic measurements with a detailed inelastic Neutron Scattering investigation. The strategy for assigning anisotropy axes in NaCo3 is equivalent to the one used in the angular trinuclear Co(super II) cluster Co3W and equally successful.

Details

Language :
English
ISSN :
00201669
Volume :
44
Issue :
10
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.142223884