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Homolytic bond dissociation energies of the benzylic C-H bonds in radical anions and radical cations derived from fluorines, triphenylmethanes, and related compounds
- Source :
- Journal of the American Chemical Society. Dec 2, 1992, Vol. 114 Issue 25, p9787, 9 p.
- Publication Year :
- 1992
-
Abstract
- An approach for the estimation of homolytic bond dissociation energies of the benzylic C-H bonds in radical anions and radical cations is developed. The method is employed for radical anions derived from 19 fluorines, 15 triphenylmethanes, p-nitrotoluene, diphenylmethane, bis(4-nitrophenyl)methane and three xanthenes. The bond dissociation energy values for the C-H bonds in the various radical anion and cation derivatives are provided.
Details
- ISSN :
- 00027863
- Volume :
- 114
- Issue :
- 25
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.14168082