Hydrogen-bond tuning of macroscopic transport properties from the neutral molecular component site along the series of metallic organic-inorganic solvates (BEDT-TTF)4Re6Se5Cl9.(guest=DMF,THF,dioxane)

A study was done on the neutral molecular component site along the series of metallic organic-inorganic solvates. The series of single crystals composed of a monoanion which is a hexanuclear chalcohalide rhenium cluster and the neutral guest molecules are dimethylformamide. The compounds possess similar basic structural organization in which conducting organic cation radical slabs are sandwiched by inorganic cluster monoanion layers.