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Boron atoms with acetylene. Ab initio calculated and observed isotropic infrared spectra of the borirene radical BC2H2: a fingerprint match
- Source :
- Journal of the American Chemical Society. March 24, 1993, Vol. 115 Issue 6, p2510, 2 p.
- Publication Year :
- 1993
-
Abstract
- The boron-acetylene reaction was studied to analyze the C-H insertion and C=C addition interreactions between the boron and acetylene atoms. Mixtures of argon/acetylene were deposited with laser-evaporated boron atoms at the target using 40 milliJoules/pulse. Calculations were performed at the MP2 level using the DZP basis set. Results indicate the presence of a strong absorption band in the mixture near the ultraviolet range.
- Subjects :
- Boron -- Research
Acetylene -- Research
Chemistry
Subjects
Details
- ISSN :
- 00027863
- Volume :
- 115
- Issue :
- 6
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.14109933