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Nitrosylated iron-thiolate-sulfinate complexes with {Fe(NO)}(super 6/7) electronic cores: Relevance to the transformation between the active and inactive NO-bound forms of iron-containing nitrile hydratases
- Source :
- Inorganic Chemistry. Sept 19, 2005, Vol. 44 Issue 19, 6670-6679
- Publication Year :
- 2005
-
Abstract
- The reactivity of the {Fe(NO)}(super n) iron-thiolate and iron-sulfinate nitrosyl complexes toward O2, the influence of sulfinate ligand on Fe-N-O bonding and on the electronic structure of the {Fe(NO)}(super 6/7) core, and the photochemical interconversion between iron-thiolate and iron-sulfinate-thiolate nitrosyl complexes are studied. Insights into the interconversion pathways between the active and inactive NO-bound forms of Fe-containing nitrile hydratase are presented.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 19
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.140151770