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Homolytic bond dissociation energies of the acidic C-H bonds in alpha-substituted and 10-substituted 9-methylanthracenes and their related radical anions
- Source :
- Journal of Organic Chemistry. May 21, 1993, Vol. 58 Issue 11, p3050, 9 p.
- Publication Year :
- 1993
-
Abstract
- Bond dissociation energies of the acidic C-H bonds in 13 alpha-substituted 9-mehtylanthracenes and 11 10-substituted methylanthracenes. This included equilibium acidity (pKHA), reduction potential Ere(HA), oxidation potential Eox(HA), and oxidation potential of conjugate anions Eox(A-) in dimethyl sulfoxide solution. Equilibrium acidities were linearly correlated with Hammettsigma negative constants. Combinations of equilibrium acidities were used to determine homolytic bond dissociation energies.
Details
- ISSN :
- 00223263
- Volume :
- 58
- Issue :
- 11
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.14010076