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A C2-symmetric, living alpha-dilmine Ni(II) catalyst: Regioblock copolymers from propylene

Authors :
Cherian, Anna E.
Rose, Jeffrey M.
Lobkovsky, Emil B.
Coates, Geoffrey W.
Source :
Journal of the American Chemical Society. Oct 12, 2005, Vol. 127 Issue 40, 13770-13771
Publication Year :
2005

Abstract

A C2-symmetric Ni(II) catalyst that exhibits both living behavior and isospecificity in the polymerization of propylene is reported. Regioblock copolymers can be synthesized by changing T(sub rxn) during polymerization.

Details

Language :
English
ISSN :
00027863
Volume :
127
Issue :
40
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.140026383