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Two halogeno(cyano)cuprates with long-lived and strong luminescence

Authors :
Xi Liu
Guo Guo-Cong
A-Qing Wu
Li-Zhen Cai
Jin-Shun Huang
Source :
Inorganic Chemistry. June 13, 2005, Vol. 44 Issue 12, p4282, 5 p.
Publication Year :
2005

Abstract

Solvothermal reactions of copper(I) cyanide with tetramethylammonium salts in anhydrous tetrahydrofuran (THF) lead to two novel halogeno(cyano)cuprates namely [Me4N][Cu3(CN)2Br2] with a 1 - D ribbon motif and [Me4N]2[Cu4(CN)5CI] and with a 3-D nanoporous framework. The optical and luminescent studies indicate that both the complexes are potential materials for semiconductors and long-lived highly luminescent material.c

Details

Language :
English
ISSN :
00201669
Volume :
44
Issue :
12
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.138792787