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Reduction of Tris(benzene-1,2-dithiolate) molybdenum(VI) by water. A functional Mo-Hydroxylase analogue system
- Source :
- Inorganic Chemistry. June 13, 2005, Vol. 44 Issue 12, p4106, 3 p.
- Publication Year :
- 2005
-
Abstract
- Mo(super VI)(S2C6H4) reacts cleanly and completely with H(sub 2)O in THF to afford [H(sub 3)](super +)[Mo(super V)(S2C6H4)3](super -1). The Mo(super VI)(S2C6H4)3 reduction is acceralated by the presence of PPh3 and affords OPP3.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 12
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.138792635