Back to Search
Start Over
Definitive assignments of the visible-near-IR bands of porphyrin-naphthalocyanine rare-earth sandwich double- and triple-decker compounds by magnetic circular dichroism spectroscopy
- Source :
- Inorganic Chemistry. May 30, 2005, Vol. 44 Issue 11, p3818, 9 p.
- Publication Year :
- 2005
-
Abstract
- A series of heteroleptic rare-earth sandwich complexes [M(Nc)(OEP)]( where M= La, Nd, Eu , Dy and Lu; Nc=2,3-naphthalocyaninate; OEP= octaethylporphyrinate] is investigated by electronic absorption and magnetic circular dichroism (MCD) spectroscopy. The electronic absorption spectra of the neutral forms show two characteristic transitions in the near-IR region, both of which were systematically shifted depending on the size of their central metal.
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 11
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.136189734