CF2Cl2 decomposition over nanocrystalline MgO: Evidence for long induction periods

Authors :: Mishakov, Ilya V.
Zaikovskii, Vladimir I.
Heroux, David S.
Volodin, Alexander M.
Parmon, Valentin N.
Bedilo, Alexander F.
Chesnokov, Vladimir V.
Martyanov, Igor N.
Filimonova, Svetlana V.
Klabunde, Kenneth J.
Source :: Journal of Physical Chemistry B. April 21, 2005, Vol. 109 Issue 15, 6982-6989
Publication Year :: 2005
Abstract: A study is carried out on the reaction between CF2Cl with nanoscale MgO at 325 degree Celsius and higher temperature. The reaction results in the formation of MgFe2 as a predominant solid product, with CCl4, and CO2 formed as the main gaseous products when excess of halocarbons is used.

Subjects :: Thermodynamics -- Analysis
Decomposition (Chemistry) -- Analysis
Dichlorodifluoromethane -- Properties
Dichlorodifluoromethane -- Spectra
Dichlorodifluoromethane -- Chemical properties
X-ray spectroscopy -- Analysis
Magnesium oxide -- Properties
Magnesium oxide -- Spectra
Magnesium oxide -- Chemical properties
Chemicals, plastics and rubber industries

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