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Toward an easy access to dendrimer-like poly(ethylene oxide)s
- Source :
- Journal of the American Chemical Society. August 10, 2005, Vol. 127 Issue 31, 10956-10966
- Publication Year :
- 2005
-
Abstract
- Dendrimer-like poly(ethylene oxide)s (PEOs) is synthesized by an iterative divergent approach combining anionic polymerization of ethylene oxide from multi-hydroxylated precursors and branching reactions of PEO chain ends. Partial deprotonation of the hydroxyls is found to be crucial for a successful polymerization of ethylene oxide at room temperature using dimethyl sulfoxide (DMSO) as a solvent.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 127
- Issue :
- 31
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.135558314