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Reduction of inner sulfonium salts, thioethers, and sulfones derived from closo-[B12H12](super 2-) by lithium in methylamine: A new route to mercaptododecaborates

Authors :
Kultyshev, Roman G.
Liu, Shengming
Shore, Sheldon G.
Source :
Inorganic Chemistry. Dec 25, 2000, Vol. 39 Issue 26, 6094-6099
Publication Year :
2000

Abstract

The reduction of inner sulfonium salts, thioethers, and sulfones derived from closo-[B12H12](super 2-) by lithium in methylamine are studied. Results indicate that the reduction of inner methylsulfonium salts, thioethers, and sulfones derived from closo-[B12H12](super 2-) by lithium in methylamine produces the corresponding thiols.

Details

Language :
English
ISSN :
00201669
Volume :
39
Issue :
26
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.132995879