Quantum chemical and master equation simulation of the oxidation and isomerization of vinoxy radicals

Authors :: Kuwata, Keith T.
Hasson, Alam S.
Dickinson, Ray V.
Petersen, Erin B.
Valin, Lukas C.
Source :: Journal of Physical Chemistry A. March 24, 2005, Vol. 109 Issue 11, 2514-2524
Publication Year :: 2005
Abstract: The parent and substituted vinoxy radicals are key intermediates in both combustion and atmospheric chemistry. Experiment and theory indicate that vinoxy radicals react with moderate facility with molecular oxygen to form alpha-oxoperoxy radicals.

Subjects :: Oxidation-reduction reaction -- Research
Radicals (Chemistry) -- Research
Isomerization -- Research
Chemicals, plastics and rubber industries

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