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Structure and magnetism of a new hydrogen-bonded layered cobalt(II) network, constructed by the unprecedented carboxylate-phosphinate ligand [O2(C6H5)PCH2CO2](super 2-)
- Source :
- Inorganic Chemistry. March 21, 2005, Vol. 44 Issue 6, p2060, 7 p.
- Publication Year :
- 2005
-
Abstract
- A novel hybrid material of formula [CO2(pcc)2(H2O)2].H2O is obtained by hydrothermal reaction of CoCl2.6H2O with K(sub 2)pcc (H(sub 2)pcc = phenyl(carboxymethyl) phosphoric acid) at 423 K. The compound exhibits a polymeric arrangement, where cobalt metal ions, linked together by bridging carboxylate and phosphinate oxygens, form infinite chains of edge-shared CoO6 octahedra.
- Subjects :
- Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00201669
- Volume :
- 44
- Issue :
- 6
- Database :
- Gale General OneFile
- Journal :
- Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.132863421