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Unusual palladium-catalyzed silaboration of allenes using organic iodides as initiators: Mechanism and application
- Source :
- Journal of the American Chemical Society. Jan 12, 2005, Vol. 127 Issue 1, p126, 6 p.
- Publication Year :
- 2005
-
Abstract
- A new and efficient method for silaboration of allenes catalyzed by palladium complexes and initiated by organic iodides is demonstrated. The method provides a convenient and general route to various 2-silylallylboronates in good yields with excellent regio- and stereoselectivity.
- Subjects :
- Palladium -- Chemical properties
Iodides -- Chemical properties
Chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 127
- Issue :
- 1
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.132667414