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The rotational molding of a thermotropic liquid crystalline polymer

Authors :
Scribben, Eric
Baird, Donald
Source :
Polymer Engineering and Science. March, 2005, Vol. 45 Issue 3, p410, 14 p.
Publication Year :
2005

Abstract

Thermotropic liquid crystalline polymers (TLCPs) exhibit a number of mechanical and physical properties such as excellent chemical resistance, low permeability, low coefficient of thermal expansion, high tensile strength and modulus, and good impact resistance, which make them desirable as a rotationally molded storage vessel. However, there are no reports in the technical literature of the successful rotational molding of TLCPs. In this article, conditions are identified that lead to the successful rotational molding of a TLCP, Vectra B 950. First, a technique was developed to produce particles suitable for rotational molding because TLCPs cannot be ground into a free-flowing powder. Second, because the viscosity at low shear rates can be detrimental to the sintering process, coalescence experiments with isolated particles were carried out to determine the thermal and environmental conditions at which sintering should occur. These conditions were then applied to static sintering experiments to determine whether coalescence and densification of the bulk powder would occur. Finally, the powders were successfully rotationally molded into tubular structures in a single axis, lab-scale device. The density of the molded structure was essentially equivalent to the material density and the tensile strength and modulus were approximately 18 MPa and 2 GPa, respectively. POLYM. ENG. SCI., 45:410-423, 2005. [c] Society of Plastics Engineers<br />INTRODUCTION Thermotropic liquid crystalline polymers (TLCPs) exhibit a number of mechanical and physical properties that make them desirable for use in storage vessels for cryogenic or corrosive fluids. TLCPs have [...]

Details

Language :
English
ISSN :
00323888
Volume :
45
Issue :
3
Database :
Gale General OneFile
Journal :
Polymer Engineering and Science
Publication Type :
Academic Journal
Accession number :
edsgcl.131004843