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Correlating acidities, electron affinities, and bond dissociation energies. Measure one, get all three!
- Source :
- Journal of Organic Chemistry. Dec 24, 2004, Vol. 69 Issue 26, p9176, 8 p.
- Publication Year :
- 2004
-
Abstract
- A linear relation between delta-H(super degree) (sub acid)(HX), EA[X(sub .)], and BDE(HX) is shown for specific classes of compounds and only one of these quantities is needed to determine the others. The intercepts obtained from plots of delta-H(super degree) (sub acid)(HX) vs EA[X(sub .)] provide bond energies which correspond to BDE(HX) when EA[X(sub .)] = 0.
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 69
- Issue :
- 26
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.127671784