Observation of a heterogeneous source of OCIO from the reaction of CIO radicals on ice

Authors :: McKeachie, J.R.
Appel, M.F.
Kirchner, U.
Schindler, R.N.
Benter, Th.
Source :: Journal of Physical Chemistry B. Oct 28, 2004, Vol. 108 Issue 43, p16786, 12 p.
Publication Year :: 2004
Abstract: A heterogeneous source of several chlorine oxides, in particular OCIO and CICIO2, from CIO radicals passed over water-ice surfaces at low pressures is demonstrated. CIO radicals are generated in a flow system and reaction products are monitored by UV-vis absorption spectroscopy and time-of-flight mass spectrometry using electron-impact and resonance-enhanced mulitphoton ionization, respectively.

Subjects :: Absorption spectra -- Research
Chlorine oxides -- Chemical properties
Chemical reactions -- Analysis
Chemicals, plastics and rubber industries

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