Chelation-assisted hydrative dimerization of 1-alkyne forming alpha, beta-enones by an Rh(I) catalyst

Authors :: Young Jun Park
Bong-II Kwon
Jeong-Ae Ahn
Hyuk Lee
Chul-Ho Jun
Source :: Journal of the American Chemical Society. Nov 3, 2004, Vol. 126 Issue 43, 13892-13893
Publication Year :: 2004
Abstract: The chelation-assisted catalytic system with Rh(I)/2-amino-3-picoline underwent an intermolecular hydrative dimerization reaction of 1-alkyne to give alpha, beta-enones. This transformation represents a new reaction pathway for the synthesis of alpha, beta enones.

Subjects :: Chemical reactions -- Research
Catalysts -- Research
Alkanes -- Research
Alkanes -- Chemical properties
Rhodium -- Research
Rhodium -- Chemical properties
Chemistry

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