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Activation of alkenes and H2 by [Fe]-H2ase model complexes

Authors :
Xuan Zhao
Chao-Yi Chiang
Miller, Matthew L.
Rampersad, Marilyn V.
Darensbourg, Marcetta Y.
Source :
Journal of the American Chemical Society. Jan 15, 2003, Vol. 125 Issue 2, p518, 7 p.
Publication Year :
2003

Abstract

The activation of alkenes and H2 by [Fe]-H2ase model complexes is presented. It is found that the metal hydride derived from the heterolytic H2 splitting is important intermediates along the reaction path of the hydrogenases.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
2
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.125306098