U-shaped donor [bridge] acceptor systems with remarkable charge transfer fluorescent properties: An experimental and computational investigation

Authors :: Koeberg, Mattijs
Verhoeven, Jan W.
Lokan, Nigel R.
Shephard, Michael J.
Paddon-Row, Michael N.
Groot, Mattijs de
Source :: Journal of Physical Chemistry A. April 5, 2001, Vol. 105 Issue 13, p3417, 8 p.
Publication Year :: 2001
Abstract: The photoinduced intramolecular electron transfer in two donor-bridge-acceptor systems, DPN[8cy]DCV and DPMN[8cy]DCV in which the through space (TS) distance between the donor (DPN and DPMN) and DCV acceptor groups in the ground state are approximately 5.8 angstrom is studied. The fluorescence and transient absorption techniques are used for this purpose.

Subjects :: Charge transfer -- Analysis
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