Is the H2OCl(super +) ion a viable intermediate for the hydrolysis of ClONO2 on ice surface?

Authors :: Bianco, Roberto
Thompson, Ward H.
Morita, Akihiro
Hynes, James T.
Source :: Journal of Physical Chemistry A. April 5, 2001, Vol. 105 Issue 13, p3132, 8 p.
Publication Year :: 2001
Abstract: A new thermodynamic, calculation, and IR considerations that indicate the H2OCl(super +) ion is not involved in the ClONO2 hydrolysis on ice surface is presented. The IR spectra calculations providing an explicit identification of the 1650 cm(super -1) spectral feature are detailed.

Subjects :: Chlorine compounds -- Chemical properties
Hydrolysis -- Methods
Chemicals, plastics and rubber industries

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