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Thermochemistry of gaseous OSiI, OSiI2, SiI, and SiI2

Authors :
Hildenbrand, D. L.
Lau, K. H.
Baglio, J. W.
Struck, C. W
Source :
Journal of Physical Chemistry A. April 26, 2001, Vol. 105 Issue 16, 4114-4117
Publication Year :
2001

Abstract

The gaseous reaction equilibria in the Si-O-I system were investigated by mass spectrometry, leading to identification and thermochemical characterization of the species OSiI, OSiI2, SiI, and SiI2. The results for OSiI and OSiI2 were 25-30 kcal mol(Super -1) less stable than the semiempirical estimates.

Subjects

Subjects :
Mass spectrometry -- Research
Silicon -- Thermal properties
Silicon -- Chemical properties
Chemicals, plastics and rubber industries

Details

Language :
English
ISSN :
10895639
Volume :
105
Issue :
16
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.124996650

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