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Allylic alkylation versus Michael induced ring closure: chelated enolates as versatile nucleophiles
- Source :
- Journal of Organic Chemistry. Oct 1, 2004, Vol. 69 Issue 20, p6909, 4 p.
- Publication Year :
- 2004
-
Abstract
- Chelated enolates react with excellent selectivities not only in palladium-catalyzed allylic alkylations but also in Michael additions is demonstrated. Chelated amino acid ester enolates are versatile nucleophiles for both reactions giving high yields and selectivities.
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 69
- Issue :
- 20
- Database :
- Gale General OneFile
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.124923051