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Pyrazolylborate-zinc alkoxide complexes.2. Solvolytic chemistry

Authors :
Brombacher, Horst
Vahrenkamp, Heinrich
Source :
Inorganic Chemistry. Sept 20, 2004, Vol. 43 Issue 19, p6050, 4 p.
Publication Year :
2004

Abstract

The methoxides Tp (super Ph, Me) Zn-OMe and Tp (super Cum, Me) Zn-OMe are tested for their reactivity substrates that are hydrolytically cleaved with Tp*Zn-OH complexes. The findings indicated that, while the leaving group properties of the methoxide unit are essential, it is the strength of the resulting zinc-substrate bonds that decides upon the occurrence or nonoccurrences of the cleavage reactions.

Details

Language :
English
ISSN :
00201669
Volume :
43
Issue :
19
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.124768926