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Frustrated beta-chloride elimination: Selective arene alkylation by alpha-chloronorborene catalyzed by electrophilic metallocenium ion pairs
- Source :
- Journal of the American Chemical Society. Oct 6, 2004, Vol. 126 Issue 39, p12528, 13 p.
- Publication Year :
- 2004
-
Abstract
- The selective arene alkylation by alpha-chloronorborene catalyzed by electrophilic metallocenium ion pairs has been described. Control experiments and reactivity studies on each component step suggest a mechanism involving participation of the metal electrophiles in the catalytic cycle.
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 126
- Issue :
- 39
- Database :
- Gale General OneFile
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- edsgcl.124743223