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Electrocatalytic reduction of ROOH by iron porphyrins

Authors :
Collman, James P.
Kaplun, Marina
Sunderland, Christopher J.
Boulatov, Roman
Source :
Journal of the American Chemical Society. Sept 15, 2004, Vol. 126 Issue 36, 11166-11167
Publication Year :
2004

Abstract

The kinetics and the mechanism of electrocatalytic reduction of common peroxidic oxidants are reported. At ferric-Fe-(NMe) and Fe(Ac), catalytic reduction of KHSO5, PAA and CPBA is substantially faster than reduction of H2O2, which is comparable to that of TBHP.

Subjects

Subjects :
Iron compounds -- Chemical properties
Dynamics -- Research
Porphyrins -- Research
Chemistry

Details

Language :
English
ISSN :
00027863
Volume :
126
Issue :
36
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.124626180

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