Dispersed fluorescence spectroscopy of S(sub 0) formyl fluoride vibrational states

The study stated that dispersed fluorescence (DF) spectroscopy was used to record a 22500 cm(super -1) spectrum of the vibrational energy levels of formyl fluoride (HFCO) which determined harmonic frequencies and anharmonic constants of the S(sub 0) potential energy surface. The analysis of the spectrum resulted in 240 assignments, which include 196 new assignments, and 56 assignments above the approximate 17000 cm(super -1) dissociation barrier.