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Polarizing the Nazarov cyclization: Efficient catalysis under mild conditions

Authors :
He, Wei
Sun, Xiufeng
Frontier, Alison J.
Source :
Journal of the American Chemical Society. Nov 26, 2003, Vol. 125 Issue 47, p14278, 2 p.
Publication Year :
2003

Abstract

A mild, Lewis acid-catalyzed procedure for Nazarov cyclization of polarized divinyl ketones is reported. Polarization in the cyclization, by utilizing Lewis acid with chiral ligands to promote enentioselective cyclization and synthetic applications of the methodology is highlighted.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
47
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.124596086