Kinetics and mechanism for the metalation of 5,10,15120-tetrakis(pentafluorophenyl)porphyrin with bis(beta-diketonato)copper(II) complexes in supercritical dioxide and n-hexane

Authors :: Inada, Yasuhiro
Sato, Hideyuki
Kiu, Shi-jun
Horita, Taichi
Funahashi, Shigenobu
Source :: Journal of Physical Chemistry A. March 13, 2003, Vol. 107 Issue 10, p1525, 7 p.
Publication Year :: 2003
Abstract: Incorporation of copper(II) ion into fluorinated porphyrin to form the metalloporphyrin CCu(tpfpp)) was kinetically investigated using bis(beta-diketonato)copper(II) complexes (CuL2) in ScCO2 and n-hexane. The reaction mechanisms in both the solvents seemed to be similar.

Subjects :: Hexane -- Chemical properties
Copper compounds -- Chemical properties
Porphyrins -- Chemical properties
Chemicals, plastics and rubber industries

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