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Kinetics and mechanism of the addition of aliphatic amines to transient silenes

Authors :
Leigh, William
Li, Xiaojing
Source :
Journal of Physical Chemistry A. March 13, 2003, Vol. 107 Issue 10, p1517, 8 p.
Publication Year :
2003

Abstract

The kinetics and mechanism of three amines with two 1,1-diarylsilene derivatives have been studied in hexane, acetonitrile and tetrahydrofuran (THF) solution using laser flash photolysis techniques. The reactions were slower in THF as compared to the MeCN solution.

Subjects

Subjects :
Hexane -- Chemical properties
Acetonitrile -- Chemical properties
Chemicals, plastics and rubber industries

Details

Language :
English
ISSN :
10895639
Volume :
107
Issue :
10
Database :
Gale General OneFile
Journal :
Journal of Physical Chemistry A
Publication Type :
Academic Journal
Accession number :
edsgcl.124322275

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