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New linear tricobalt complex of Di(2-pyridyl)amide (dpa),[Co(sub 3)(dpa)(sub- 4)(CH(sub 3)CN][PF(sub 6)](sub 2)

Authors :
Clerac, Rodolphe
Cotton, F. Albert
Dunbar, Kim R.
Tongbu Lu
Murillo, Carlos A.
Xiaoping Wang
Source :
Inorganic Chemistry. July 10, 2000, Vol. 39 Issue 14, p3065, 6 p.
Publication Year :
2000

Abstract

Two crystalline forms of Di(2-pyridyl)amide (dpa),[Co(sub 3)(dpa)(sub- 4)(CH(sub 3)CN][PF(sub 6)](sub 2) are obtained from the same solution. Chiral crystals of both Delta and Alfa configurations have been isolated and determined by X-ray crystallography and their mirror-image circular dichroism spectra measured.

Details

Language :
English
ISSN :
00201669
Volume :
39
Issue :
14
Database :
Gale General OneFile
Journal :
Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
edsgcl.124118308