Back to Search Start Over

Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. A practical synthesis of alpha-chiral amines

Authors :
Boezio, Alessandro A.
Charette, Andre B.
Source :
Journal of the American Chemical Society. Feb 19, 2003, Vol. 125 Issue 7, p1692, 2 p.
Publication Year :
2003

Abstract

The catalytic, enantioselective addition of nucleophiles to imines is a very important process, as alpha-chiral amines play in biologically important systems. The first practical new catalytic system for the addition of dialkylzinc reagents to N-diphenylphosphinoylimines is reported.

Details

Language :
English
ISSN :
00027863
Volume :
125
Issue :
7
Database :
Gale General OneFile
Journal :
Journal of the American Chemical Society
Publication Type :
Academic Journal
Accession number :
edsgcl.123818651